Synthesis, structure, and magnetic properties of the cobalt(II) 1,3,5-benzenetricarboxylate layered coordination polymer

D. N. Dybtsev; M. P. Yutkin; E. V. Peresypkina; A. V. Virovets; Y. Hasegawa; H. Nishihara; V. P. Fedin

doi:10.1007/s11172-007-0277-8

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Synthesis, structure, and magnetic properties of the cobalt(II) 1,3,5-benzenetricarboxylate layered coordination polymer

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Synthesis, structure, and magnetic properties of the cobalt(II) 1,3,5-benzenetricarboxylate layered coordination polymer

D. N. Dybtsev, M. P. Yutkin, E. V. Peresypkina, A. V. Virovets, Y. Hasegawa, H. Nishihara and V. P. Fedin

Russian chemical bulletin, Vol.56(9), pp.1782-1786

01/09/2007

DOI: https://doi.org/10.1007/s11172-007-0277-8

Abstract

Chemistry

Chemistry, Multidisciplinary

Physical Sciences

Science & Technology

The reaction of Co(NO3)(2)center dot 6H(2)O with 1,3,5-benzenetricarboxylic acid (H(3)btc, trimesic acid) in DMF at 100 degrees C afforded the coordination polymer [Co-3(dmf)(6)(btc)(Hbtc)(H(2)btc)]center dot center dot 9H(2)O (1) (dmf is N,N'-dimethylformamide, DMF). According to the X-ray diffraction study, the metal-organic coordination polymer is composed of planar honeycomb (6,3) networks, in which the organic benzenetricarboxylate anions and the inorganic Co-2 cations play a role of three-connected nodes. Disordered water molecules are intercalated between the layers. A study of the magnetic properties showed the presence of a weak antiferromagnetic coupling between the Co2+ ions (S = 3/2).

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Title: Synthesis, structure, and magnetic properties of the cobalt(II) 1,3,5-benzenetricarboxylate layered coordination polymer
Creators - without role: D. N. Dybtsev - Nikolaev Institute of Inorganic Chemistry
M. P. Yutkin - Nikolaev Institute of Inorganic Chemistry
E. V. Peresypkina - Nikolaev Institute of Inorganic Chemistry
A. V. Virovets - Nikolaev Institute of Inorganic Chemistry
Y. Hasegawa - The University of Tokyo
H. Nishihara - The University of Tokyo
V. P. Fedin - Nikolaev Institute of Inorganic Chemistry
Publication Details: Russian chemical bulletin, Vol.56(9), pp.1782-1786
Publisher: Springer Nature
Number of pages: 5
Identifiers: 9944193508331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article