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THE CRYSTAL-STRUCTURE OF THE ORGANOSILICON P-TOLUENESULFONATE (ME3SI)3CSIPH(H)(OSO2C6H4ME-P)
Journal article   Peer reviewed

THE CRYSTAL-STRUCTURE OF THE ORGANOSILICON P-TOLUENESULFONATE (ME3SI)3CSIPH(H)(OSO2C6H4ME-P)

S S Aljuaid, AAK Alnasr, C Eaborn and P B Hitchcock
Journal of organometallic chemistry, Vol.455(1-2), pp.57-60
10/08/1993
DOI: https://doi.org/10.1016/0022-328X(93)80380-T

Abstract

Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology
A single crystal X-ray diffraction study of the title compound has shown that the geometry within the OSO2C6H4Me-p group is very similar to that in organic tosylates, but the Si-O-S angle (128.0(5)-degrees) is significantly larger than the corresponding C-O-S angle (ca. 118-degrees) in the latter species.

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