Abstract
Finding a robust catalytic system for hydrogen production via dry reforming of methane (DRM) remains a challenge. Herein, MNi0.9Zr1-xYxO3 (M = Ce, La, and La0.6Ce0.4; x = 0.00, 0.05, 0.07, and 0.09) catalyst was prepared by the sol-gel method, tested for DRM and characterized by surface area and porosity, X-ray diffraction, H-2-temperature programmed reduction, thermogravimetry, and transmission electron microscopy. In La0.6Ce0.4NiO3 catalyst, the substitution of Ni by 0.1% Zr results in a constant high catalytic activity (83% hydrogen yield at 800 degrees C) due to the presence of reducible "NiO-species interacted strongly with the support" (stable metallic Ni over reduced catalyst) and redox input by ceria phase for laying instant lattice oxygen during lag-off period of CO2. Substitution of Ni by Zr and Y in the CeNiO3 catalyst system nurtures Ni3Y (providing highly stable metallic Ni for CH4 decomposition) and cerium yttrium oxide phases (providing strong redox input). CeNi0.9Zr0.01Y0.09O3 shows 85% H-2 yield at 800 degrees C.