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The synthesis of polymeric sulfides by reaction of dihaloalkanes with sodium sulfide
Journal article   Peer reviewed

The synthesis of polymeric sulfides by reaction of dihaloalkanes with sodium sulfide

Keith Smith, Gamal A. El-Hiti and Ali J. Al-Zuhairi
Journal of sulfur chemistry, Vol.32(6), pp.521-531
01/12/2011

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Several poly(alkylene sulfide)s have been synthesized in excellent yields from reactions of alpha,omega-dibromoand/or alpha,omega-dichloroalkanes with sodium sulfide nonahydrate under reflux conditions. The procedure is general, simple and convenient for the production of various poly(alkylene sulfide)s and the way reaction parameters influence the properties of the polymers formed has been examined.

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