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The use of a well-defined surface organometallic complex as a probe molecule: [(≡SiO)Ta(V)Cl2Me2] shows different isolated silanol sites on the silica surface
Journal article   Peer reviewed

The use of a well-defined surface organometallic complex as a probe molecule: [(≡SiO)Ta(V)Cl2Me2] shows different isolated silanol sites on the silica surface

Yin Chen, Bin Zheng, Edy Abou-Hamad, Ali Hamieh, Bilel Hamzaoui, Kuo-wei Huang and Jean-marie Basset
Chemical communications (Cambridge, England), Vol.50(79), pp.11721-11723
11/10/2014
DOI: https://doi.org/10.1039/c4cc04277h
PMID: 25142307

Abstract

Ta(V)Cl2Me3 reacts with silica(700) and produces two different [(≡SiO)Ta(V)Cl2Me2] surface organometallic species, suggesting a heterogeneity of the highly dehydroxylated silica surface, which was studied with a combined experimental and theoretical approach.

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