Abstract
Co:ZnO (CZnO) ferromagnetic semiconductor layers are coated on the surface of glass and Si substrates by Magnetron Sputter Deposition Method (MSDM) with variable N2/Ar gas flow ratio. N2/Ar flow ratio varies from 5 sccm to 20 sccm, keeping the Ar gas flow constant (at 30 sccm). Sample's surface topography-composition, structure and optic properties are characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and ultraviolet–visible (UV/Vis) spectrophotometry. CZnO/p-Si structure exhibits both rectifying and photovoltaic behavior. Kohlrausch decay function is used to model the photocurrent transient curve and the associated relaxation process. The values of the photo charge density (ρph) and the relaxation time constant (τ0) are found to be 1.02 × 1011 Coul/cm−2 and 1.1 × 104 s, respectively. These findings suggest that CZnO/p-Si structure can be used in photodetector applications. The photoconductivity of the device can be tuned with the N2/Ar flow ratio since the property of CZnO thin films deposited from 3% Co doped ZnO target is dependent on the N2 and Ar atmosphere.
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•We have fabricated nanostructure CZnO by sputtering on the p-Si.•The photocurrent in the reverse bias voltage is increased by increasing photo-illumination intensity.•The structure behaves as a photodiode.•Kohlrausch decay function was used to model photocurrent transient data.