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Theoretical insights into the superior activity of gold catalysts and reactions of organogold intermediates with electrophiles
Journal article   Peer reviewed

Theoretical insights into the superior activity of gold catalysts and reactions of organogold intermediates with electrophiles

A. Stephen K. Hashmi, Markus Pernpointner and Max M. Hansmann
Faraday discussions, Vol.152, pp.179-184
01/01/2011
DOI: https://doi.org/10.1039/c1fd00029b
PMID: 22455045

Abstract

Chemistry Chemistry, Physical Physical Sciences Science & Technology
Three fundamental steps of homogeneous gold catalysis, the activiation of substrates by coordination to gold, the protodeauration after the nucleophilic addition and the transmetalation to palladium in palladium-catalysed C-C bond forming reactions using organogold intermediates have been studied and discussed in detail.

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