Abstract
Trace metals pollution, distribution and associated health risk were evaluated in the arid coastal aquifer, Hada Al-Sham, Western Saudi Arabia using an integrated approach namely heavy metal pollution index (HPI), contamination index (Cd), health risk assessment (HRA) model and multivariate statistical analysis. Groundwater samples (n = 47) were analysed for EC, pH, TDS, Ag, Al, B, Ba, Co, Cd, Cr, Cu, Fe, Mo, Ni, Pb, V and Zn. Groundwater is mostly alkaline (72%) with high salinity (TDS >1500 mg/l, 77%). Average trace metals concentrations are in the dominance order of B > Cu > Al > Mo > Pb > V > Ba > Zn > Ni > Cr > Fe > Ag. Groundwater (100% wells) is unsafe for drinking based on V, Mo, Al concentrations followed by the Pb (96%), B (91%), Ni (72%), Cr (23%), Cu (17%) and Ag (6%), which exceeded the WHO and USEPA prescribed limits. Results of HPI and Cd also implied the high contamination and enhanced level of metals in the groundwater. Chronic daily intake (CDIoral), hazard quotient (HQ) and total hazard quotient (THQ) were employed for health risk assessment. HQ values reveal that 100% (Al, Mo), 85% (Cu), 21% (B), 13% (Cr) and 6% (Pb) of samples exceeded the recommended limit (>1), which can cause an adverse health risk to adult and children. Pearson correlation, principal components analyses, and Hierarchical cluster analysis justified that aluminium silicates weathering and Fe oxides/hydroxides dissolution (Pb, Cr, Ni, Fe, Ag, Al, Mo and V), evaporation, anthropogenic input (Cu and B) and dissolution of carbonate and sulphate minerals (Ba and Zn) controlled the water chemistry in this aquifer. This study recommends a proper treatment of the groundwater to be safe for various uses. The comprehensive approach, employed here, is applicable to any arid aquifers worldwide.
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•HPI, Cd, HRA model and MSA were employed to assess trace metals (TM) pollution in Groundwater (GW).•GW is unsafe for drinking based on V, Mo, Al, Pb, B, Ni, Cr and Cu concentrations.•HPI and Cd index implied the high contamination and metals enhancement in the GW.•CDIoral and HQ justified that GW causes adverse health risk to adult and children.•Mineral dissolution, evaporation and anthropogenic input governed TM chemistry in GW.