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Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity
Journal article   Peer reviewed

Trianglamine-Based Supramolecular Organic Framework with Permanent Intrinsic Porosity and Tunable Selectivity

Arnaud Chaix, Georges Mouchaham, Aleksander Shkurenko, Phuong Hoang, Basem Moosa, Prashant M. Bhatt, Karim Adil, Khaled N. Salama, Mohamed Eddaoudi and Niveen M. Khashab
Journal of the American Chemical Society, Vol.140(44), pp.14571-14575
07/11/2018
PMID: 30293426

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Here we introduce for the first time a metal-free trianglamine-based supramolecular organic framework, T-SOF-1, with permanent intrinsic porosity and high affinity to CO2. The capability of tuning the pore aperture dimensions is also demonstrated by molecular guest encapsulation to afford excellent CO2/CH4 separation for natural gas upgrading.

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