Sign in
Back
Trigonal prism or octahedron: the conformational change of a dendritic six-node ligand in MOFs
Journal article   Peer reviewed

Trigonal prism or octahedron: the conformational change of a dendritic six-node ligand in MOFs

Jiangtao Jia, Fuxing Sun, Heping Ma, Lei Wang, Kun Cai, Zheng Bian, Lianxun Gao and Guangshan Zhu
Journal of materials chemistry. A, Materials for energy and sustainability, Vol.1(35), pp.10112-10115
01/01/2013
DOI: https://doi.org/10.1039/c3ta11840a

Abstract

Chemistry Chemistry, Physical Energy & Fuels Materials Science Materials Science, Multidisciplinary Physical Sciences Science & Technology Technology
A new dendritic aromatic six-node ligand has been used to construct a MOF. It takes an octahedral and trigonal prismatic conformation in JUC-103 and JUC-104, respectively. JUC-103 exhibits high ethane uptake and has the separation ability for ethane to nitrogen. JUC-104 has an unusual (6,12)-connected CaSi2 topology.

Metrics

1 Record Views

Details