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UV, H-1 NMR studies and a semiempirical MO calculations of some substituted phenylthiomethyl benzoic acid derivatives
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UV, H-1 NMR studies and a semiempirical MO calculations of some substituted phenylthiomethyl benzoic acid derivatives

E A Hamed, A A ElBardan, G A Gohar and A N Asaad
Spectroscopy letters, Vol.29(4), pp.549-564
01/01/1996

Abstract

Science & Technology Spectroscopy Technology
The effect of substituents on the spectral behavior of some arylthiomethyl benzoic acid derivatives, the corresponding sulfoxides and sulfones were studied. The chemical shifts of ortho hydrogen of benzyl moieties gave linear correlations with Hammett constants for acid sulfides and concave curves for sulfide esters. The effect of substituents on the conformation of sulfides were discussed.

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