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Ultrasound in organic synthesis 17 mechanistic aspects of the conjugate additions to α-enones in aqueous media
Journal article   Peer reviewed

Ultrasound in organic synthesis 17 mechanistic aspects of the conjugate additions to α-enones in aqueous media

J.L. Luche, C. Allavena, C. Petrier and C. Dupuy
Tetrahedron letters, Vol.29(42), pp.5373-5374
1988

Abstract

A free radical mechanism occuring on the metal surface seems highly probable in the conjugate addition of alkyl groups to α-enones in the presence of zinc-copper couple, under sonochemical aqueous conditions. A mechanism is proposed for the addition of R group to the conjugate position of α-enones.

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