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Unexpected Synthesis of Three Components from the Reaction of 4-Chloro-3-Formylcoumarin with Hydroxylamine Hydrochloride
Journal article   Open access

Unexpected Synthesis of Three Components from the Reaction of 4-Chloro-3-Formylcoumarin with Hydroxylamine Hydrochloride

Ahmed Elkhateeb, Ashwag S. Alshehri, Gilbert Kirsch and Sh. H. Abdel-Hafez
Oriental journal of chemistry, Vol.32(1), pp.379-384
2016

Abstract

Biochemistry & Molecular Biology Chemistry Chemistry, Multidisciplinary Life Sciences & Biomedicine Physical Sciences Science & Technology
A mild and simple oximation reaction of 4-chloro-3-formylcoumarin with hydroxylamine hydrochloride in basic medium gave unexpected three components via oxime. Those compounds were separatedin good yields by preparative TLC and by chemical means using differentreaction conditions. IR, H-1 NMR, C-13 NMR and mass spectral data confirmed the structure of the separated compounds.
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https://doi.org/10.13005/ojc/320142View
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