Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes

Anish Cyriac; Jong Yeob Jeon; Jobi Kodiyan Varghese; Ji Hae Park; Soo Young Choi; Young Keun Chung; Bun Yeoul Lee

doi:10.1039/c2dt11871h

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Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes

Journal article

Peer reviewed

Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes

Anish Cyriac, Jong Yeob Jeon, Jobi Kodiyan Varghese, Ji Hae Park, Soo Young Choi, Young Keun Chung and Bun Yeoul Lee

Dalton transactions : an international journal of inorganic chemistry, Vol.41(5), pp.1444-1447

01/01/2012

DOI: https://doi.org/10.1039/c2dt11871h

PMID: 22159296

Abstract

Chemistry

Chemistry, Inorganic & Nuclear

Physical Sciences

Science & Technology

Contrary to the stereotype, Jacobsen's catalyst, chiral (salcy)Co(III)OAc adopts an unusual binding mode. The tetradentate {ONNO} ligand does not form a square plane but wraps cobalt in a cis-beta fashion while acetate is chelating.

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Title: Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes
Creators - without role: Anish Cyriac - Ajou University
Jong Yeob Jeon - Ajou University
Jobi Kodiyan Varghese - Ajou University
Ji Hae Park - Ajou University
Soo Young Choi - Seoul National University
Young Keun Chung - Seoul National University
Bun Yeoul Lee - Ajou University
Publication Details: Dalton transactions : an international journal of inorganic chemistry, Vol.41(5), pp.1444-1447
Publisher: Royal Soc Chemistry
Number of pages: 4
Grant note: 2010-0028294 / Priority Research Centres through NRF MLTM of Korean government Construction Technology Innovation Program(CTIP) MEST of Korean government; Ministry of Education, Science & Technology (MEST), Republic of Korea
Identifiers: 9944430408331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article