Unusual coupling constants (n)J(Pt-195-H-1) and Pt-H-C interactions in new Schiff base complexes of N-alkyl-1-(ferrocen-1-yl)methanimine

I M Al-Najjar; A M Abdulrahman; J K Al-Refai; L A Al-Shabanah; L A Al-Mutabagani

doi:10.1023/A:1020305307606

Back

Unusual coupling constants (n)J(Pt-195-H-1) and Pt-H-C interactions in new Schiff base complexes of N-alkyl-1-(ferrocen-1-yl)methanimine

Journal article

Peer reviewed

Unusual coupling constants (n)J(Pt-195-H-1) and Pt-H-C interactions in new Schiff base complexes of N-alkyl-1-(ferrocen-1-yl)methanimine

I M Al-Najjar, A M Abdulrahman, J K Al-Refai, L A Al-Shabanah and L A Al-Mutabagani

Transition metal chemistry (Weinheim), Vol.27(7), pp.799-804

01/10/2002

DOI: https://doi.org/10.1023/A:1020305307606

Abstract

Chemistry

Chemistry, Inorganic & Nuclear

Physical Sciences

Science & Technology

A series of novel ferrocenylimine complexes of platinum(II) ethene of general formula trans-[PtCl2(eta(2)-C2H4) (imine)], imine=N-alkyl-1-(ferrocen-1-yl)methanimine, (alkyl=Me; i-Pr, i-Bu, s-Bu, t-Bu, +/-CH(Me)Ph, CH2Ph and Ph) have been prepared and characterized by elemental analysis, i.r, H-1-, C-13-n.m.r. spectra (N-15- and Pt-195-n.m.r. in part). Unusual coupling constants (3)J(Pt-195-H-1), 92-98 Hz were observed between the imino proton H-6 and platinum(II) which are too large for three bond coupling constants, thereby suggesting a Pt-H-C interaction.

Metrics

1 Record Views

Details

Title: Unusual coupling constants (n)J(Pt-195-H-1) and Pt-H-C interactions in new Schiff base complexes of N-alkyl-1-(ferrocen-1-yl)methanimine
Creators - without role: I M Al-Najjar - King Abdulaziz City for Science and Technology
A M Abdulrahman - King Abdulaziz City for Science and Technology
J K Al-Refai - King Abdulaziz City for Science and Technology
L A Al-Shabanah - Department of Chemistry, Girls College of Education, General Presidency for Girls, Riyadh, Saudi Arabia
L A Al-Mutabagani - Department of Chemistry, Girls College of Education, General Presidency for Girls, Riyadh, Saudi Arabia
Publication Details: Transition metal chemistry (Weinheim), Vol.27(7), pp.799-804
Publisher: KLUWER ACADEMIC PUBL
Number of pages: 6
Identifiers: 9918748408331
Academic Unit: King Abdulaziz City for Science & Technology; Princess Nourah bint Abdulrahman University
Language: English
Resource Type: Journal article