Abstract
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•2D GDY is an excellent carbon-based catalyst support.•Main strategies for loading catalysts on GDY support are summarized.•GDY mainly functions as an electron or hole transfer material in photocatalysis.•GDY improves electron transfer and reaction kinetics in electrocatalysis.
The development of carbon materials brings a new two-dimensional catalyst support, graphdiyne (GDY), which is attracting increasing interest in the field of catalysis. This article presents a systematical review of recent studies about the characteristics, design strategies, and applications of GDY-supported catalysts. The sp- and sp2-hybridized carbon, high electrical conductivity, direct band gap, and high intrinsic carrier mobility are key characteristics for GDY to serve as a competitive catalyst support. Hydrothermal method (or solvothermal method), GDY in-situ growth, and electrochemical deposition are commonly used to load catalysts on GDY support. In the applications of GDY-supported photocatalysts, GDY mainly serves as an electron or hole transfer material. For the electrocatalytic hydrogen production, the unique electronic structure and high electrical conductivity of GDY can promote the electron transfer and water splitting kinetics. This review is expected to provide meaningful insight and guidance for the design of GDY-supported catalysts and their applications.