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Using sodium acetate for the synthesis of [Au(NHC)X] complexes
Journal article   Peer reviewed

Using sodium acetate for the synthesis of [Au(NHC)X] complexes

Thomas Scattolin, Nikolaos Tzouras, Laura Falivene, Luigi Cavallo and Steven P. Nolan
Dalton transactions : an international journal of inorganic chemistry, Vol.49(28), pp.9694-9700
21/07/2020
DOI: https://doi.org/10.1039/d0dt02240c
PMID: 32613988

Abstract

Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology
The role of sodium acetate in the synthesis of [Au(NHC)Cl] complexes was examined. The use of this base was also investigated for the activation of C-H and S-H bonds by experimental and computational methods. The synthetic use of NaOAc to assemble these complexes is applicable to a wide range of NHCs and proceeds under air, under mild conditions and using technical grade green solvents.

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