Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media

Alan.R. Katritzky; Navayath Shobana; Philip A. Harris

doi:10.1016/S0040-4039(00)92139-7

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Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media

Journal article

Peer reviewed

Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media

Alan.R. Katritzky, Navayath Shobana and Philip A. Harris

Tetrahedron letters, Vol.32(34), pp.4247-4248

1991

DOI: https://doi.org/10.1016/S0040-4039(00)92139-7

Abstract

aluminum

aqueous alkylation

benzotriazole

bismuth

In the presence of bismuth(III) chloride-metallic aluminum, alkyl as well as allyl halides react with N-(alkylamino)benzotriazoles at 20°C in THF-water to give the corresponding homoalkylated amines in high yields. In the presence of BiCl 3-Al, alkyl halides react with N-(alkylamino)-benzotriazoles at 20°C in THF-water to give the corresponding homoalkylated amines in high yields.

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Title: Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media
Creators - without role: Alan.R. Katritzky - University of Florida
Navayath Shobana - University of Florida
Philip A. Harris - University of Florida
Publication Details: Tetrahedron letters, Vol.32(34), pp.4247-4248
Publisher: Elsevier Ltd
Identifiers: 9939978108331
Academic Unit: King Abdulaziz University
Language: English
Resource Type: Journal article