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Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation
Journal article   Peer reviewed

Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation

Mohamad El Eter, Bilel Hamzaoui, Edy Abou-Hamad, Jeremie D. A. Pelletier and Jean-Marie Basset
Chemical communications (Cambridge, England), Vol.49(41), pp.4616-4618
21/05/2013
DOI: https://doi.org/10.1039/c3cc40385h
PMID: 23586075

Abstract

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
Grafting of Zr(NMe2)(4) on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2)(eta 2NMeCH2). 2D solid-state NMR (H-1-C-13 HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand.

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