Well-defined mono(η(3)-allyl)nickel complex ≡MONi(η(3)-C3H5) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles

Lidong Li; Edy Abou-Hamad; Dalaver H Anjum; Lu Zhou; Paco V Laveille; Lyndon Emsley; Jean-Marie Basset

doi:10.1039/c4cc02962c

Back

Well-defined mono(η(3)-allyl)nickel complex ≡MONi(η(3)-C3H5) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles

Journal article

Peer reviewed

Well-defined mono(η(3)-allyl)nickel complex ≡MONi(η(3)-C3H5) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles

Lidong Li, Edy Abou-Hamad, Dalaver H Anjum, Lu Zhou, Paco V Laveille, Lyndon Emsley and Jean-Marie Basset

Chemical communications (Cambridge, England), Vol.50(57), pp.7716-7719

21/07/2014

DOI: https://doi.org/10.1039/c4cc02962c

PMID: 24901247

Abstract

Analytical chemistry

Chemical Sciences

Preparing evenly-dispersed small size nickel nanoparticles over inert oxides remains a challenge today. In this context, a versatile method to prepare supported small size nickel nanoparticles (ca. 1-3 nm) with narrow size distribution via a surface organometallic chemistry (SOMC) route is described. The grafted mono(η(3)-allyl)nickel complexes ≡MONi(η(3)-C3H5) (M = Si or Al) as precursors are synthesized and fully characterized by elemental analysis, FTIR spectroscopy and paramagnetic solid-state NMR.

Metrics

1 Record Views

See more details

Details

Title: Well-defined mono(η(3)-allyl)nickel complex ≡MONi(η(3)-C3H5) (M = Si or Al) grafted onto silica or alumina: a molecularly dispersed nickel precursor for syntheses of supported small size nickel nanoparticles
Creators - without role: Lidong Li - King Abdullah University of Science and Technology
Edy Abou-Hamad - King Abdullah University of Science and Technology
Dalaver H Anjum - King Abdullah University of Science and Technology
Lu Zhou - KAUST Catalysis Center
Paco V Laveille - King Abdullah University of Science and Technology
Lyndon Emsley - Université de Lyon
Jean-Marie Basset - King Abdullah University of Science and Technology
Publication Details: Chemical communications (Cambridge, England), Vol.50(57), pp.7716-7719
Publisher: Royal Society of Chemistry
Identifiers: 9943602008331
Academic Unit: King Abdullah University of Science & Technology
Language: English
Resource Type: Journal article