The first generation of the benzotriazol-1-ylmethyl radical (3) is reported from S-(1H-1,2,3-benzotriazol-1-ylmethyl)-O-ethylcarbonodithioate (1). Subsequent additions of radical (3) to a variety of olefins are demonstrated.
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Xanthate mediated generation of the benzotriazol-1-ylmethyl radical and its subsequent addition to a variety of olefins