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rac-(3S,4Z)-3-Chloro-4-[2-(3-fluorobenzylidene)hydrazinylidene]-1-methyl-3,4-dihydro-1H-2 lambda(6),1-benzothiazine-2,2-dione
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rac-(3S,4Z)-3-Chloro-4-[2-(3-fluorobenzylidene)hydrazinylidene]-1-methyl-3,4-dihydro-1H-2 lambda(6),1-benzothiazine-2,2-dione

Muhammad Shafiq, M. Nawaz Tahir, Islam Ullah Khan and Saeed Ahmad
Acta crystallographica. Section E, Crystallographic communications, Vol.68(6), p.O1787
01/06/2012
PMID: 22719564

Abstract

Crystallography Physical Sciences Science & Technology
In the title compound, C16H13ClFN3O2S, the dihedral angle between the benzene rings is 4.47 (3)degrees. The conformation of the thiazine ring is a half-chair and the Cl atom is in an axial orientation. In the crystal, molecules are linked by C-H center dot center dot center dot F interactions, generating C(12) chains propagating in [011]. Aromatic pi-pi stacking interactions [centroid-centroid separations = 3.753 (2) and 3.758 (2) angstrom] also occur.
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https://doi.org/10.1107/S1600536812021654View
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